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Match the following. -Q = K


A) Reaction will favor formation of reactants.
B) Reaction does not strongly favor reactants or products.
C) Reaction favors formation of more products.
D) Reaction has a larger amount of products than reactants.
E) Reaction is at equilibrium.

F) A) and C)
G) A) and B)

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Consider the following reaction: Xe(g) + 2 F2(g) → XeF4(g) A reaction mixture initially contains 2.24 atm Xe and 4.27 atm F2.If the equilibrium pressure of Xe is 0.34 atm,find the equilibrium constant (Kp) for the reaction.


A) 25
B) 0.12
C) 0.99
D) 8.3
E) 0.040

F) A) and B)
G) C) and D)

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of H2. D2(g) + H2(g) ⇌ 2 HD(g) Kp = 1.80 P(D2) eq = 1.1 × 10-3 atm P(HD) eq = 2.7 × 10-3 atm


A) 2.7 atm
B) 1.4 atm
C) 0.73 atm
D) 3.7 × 10-3 atm
E) 8.1 × 10-4 atm

F) All of the above
G) C) and D)

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [H2]eq = 0.14 M,[I2]eq = 0.39 M,[HI]eq = 1.6 M. H2(g) + I2(g) ⇌ 2 HI(g)


A) 2.1 × 10-2
B) 29
C) 47
D) 3.4 × 10-2
E) 8.7 × 10-2

F) A) and D)
G) A) and C)

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The decomposition of ammonia is: 2 NH3(g) ⇌ N2(g) + 3 H2(g) .If Kp is 1.5 × 103 at 400°C,what is the partial pressure of ammonia at equilibrium when N2 is 0.10 atm and H2 is 0.15 atm?


A) 2.2 × 10-7 atm
B) 4.7 × 10-4 atm
C) 2.1 × 103 atm
D) 4.4 × 106 atm

E) B) and D)
F) C) and D)

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The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant. N2O4(g) ⇌ 2 NO2(g) Kc = 1.46 3 N2O4(g) ⇌ 6 NO2(g) Kc = ?


A) 2.13
B) 0.685
C) 3.11
D) 1.46
E) 1.13

F) None of the above
G) A) and E)

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The equilibrium constant,Kp,equals 3.40 for the isomerization reaction: Cis-2-butene ⇌ trans-2-butene. If a flask initially contains 0.250 atm of cis-2-butene and 0.145 atm of trans-2-butene,what is the equilibrium pressure of each gas?


A) P(cis-2-butene) = 0.0426 atm and P(trans-2-butene) = 0.145 atm
B) P(cis-2-butene) = 0.0471 atm and P(trans-2-butene) = 0.160 atm
C) P(cis-2-butene) = 0.0735 atm and P(trans-2-butene) = 0.250 atm
D) P(cis-2-butene) = 0.0898 atm and P(trans-2-butene) = 0.305 atm

E) None of the above
F) A) and B)

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Consider the following reaction: COCl2(g) ⇌ CO(g) + Cl2(g0 A reaction mixture initially contains 1.6 M COCl2.Determine the equilibrium concentration of CO if Kc for the reaction at this temperature is 8.33 × 10-4.Calculate this based on the assumption that the answer is negligible compared to 1.6.


A) 4.2 × 10-4 M
B) 1.5 × 10-3 M
C) 3.7 × 10-2 M
D) 2.1 × 10-2 M
E) 1.3 × 10-3 M

F) A) and C)
G) C) and E)

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An equilibrium mixture of CO,O2 and CO2 at a certain temperature contains 0.0010 M CO2 and 0.0100 M O2.At this temperature,Kc equals 1.4 × 102 for the reaction: 2 CO(g) + O2(g) ⇌ 2 CO2(g) . What is the equilibrium concentration of CO?


A) 7.1 × 10-7 M
B) 8.4 × 10-4 M
C) 1.4 × 10-2 M
D) 1.2 × 10-1 M

E) B) and C)
F) All of the above

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What is the equilibrium constant (Kc) for the reaction H2(g) + I2(g) ⇌ 2HI(g) (Equilibrium concentrations are: [HI] = 1.17 M;[H2] = 0.165 M;[I2] = 0.165 M)


A) 0.020
B) 43.0
C) 50.0
D) 0.030

E) A) and B)
F) A) and C)

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At a certain temperature the equilibrium constant,Kc,equals 0.11 for the reaction: 2 ICl(g) ⇌ I2(g) + Cl2(g) . What is the equilibrium concentration of ICl if 0.45 mol of I2 and 0.45 mol of Cl2 are initially mixed in a 2.0-L flask?


A) 0.14 M
B) 0.17 M
C) 0.27 M
D) 0.34 M

E) None of the above
F) A) and C)

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Express the equilibrium constant for the following reaction. PCl5(g) ⇌ PCl3(g) + Cl2(g)


A) K = Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g) ⇌ PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)  A) K =   B) K =   C) K =   D) K =   E) K =
B) K = Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g) ⇌ PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)  A) K =   B) K =   C) K =   D) K =   E) K =
C) K = Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g) ⇌ PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)  A) K =   B) K =   C) K =   D) K =   E) K =
D) K = Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g) ⇌ PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)  A) K =   B) K =   C) K =   D) K =   E) K =
E) K = Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g) ⇌ PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)  A) K =   B) K =   C) K =   D) K =   E) K =

F) B) and D)
G) A) and E)

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The reaction below has a Kp value of 41.What is the value of Kc for this reaction at 400 K? N2(g) + 3 H2(g) ⇌ 2 NH3(g)


A) 2.4 × 10-2
B) 4.4 × 104
C) 41
D) 2.3 × 10-5
E) 1.9 × 104

F) A) and B)
G) C) and E)

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of CO2(g) . NH2COONH4(s) ⇌ 2 NH3(g) + CO2(g) Kc = 1.58 × 10-8 [NH3]eq = 2.9 × 10-3 M


A) 0.053 M
B) 4.6 × 10-11 M
C) 1.9 × 10-3 M
D) 5.4 × 10-6 M
E) 0.022 M

F) C) and D)
G) B) and E)

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The equilibrium constant (Kc) for the reaction N2O4(g) ⇌ 2 NO2 (g) is 5.85 × 10-3 at 10°C.A reaction mixture has 0.025 M of N2O4 and 0.033 M of NO2 at time t.What statement is correct for this reaction at time t?


A) The reaction goes to the left.
B) The reaction is in equilibrium.
C) The reaction goes to the right.
D) The reaction is very slow.

E) A) and B)
F) None of the above

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Which of the following statements is true?


A) If Q < K,it means the reverse reaction will proceed to form more reactants.
B) If Q > K,it means the forward reaction will proceed to form more products.
C) If Q = K,it means the reaction is at equilibrium.
D) All of the above are true.
E) None of the above are true.

F) A) and B)
G) B) and C)

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Consider the following reaction at equilibrium.What effect will increasing the pressure of the reaction mixture have on the system? 2 H2S(g) + 3 O2(g) ⇌ 2 H2O(g) + 2 SO2(g)


A) The reaction will shift to the right in the direction of products.
B) No effect will be observed.
C) The reaction will shift to the left in the direction of reactants.
D) The equilibrium constant will decrease.
E) The equilibrium constant will increase.

F) All of the above
G) A) and B)

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Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the equation: PCl5(g) ⇌ PCl3(g) + Cl2(g) At 250°C,0.125 M PCl5 is added to the flask.If Kc = 1.80,what are the equilibrium concentrations of each gas?


A) [PCl5] = 0.00765 M,[PCl3] = 0.117 M,and [Cl2] = 0.117 M
B) [PCl5] = 0.0625 M,[PCl3] = 0.335 M,and [Cl2] = 0.335 M
C) [PCl5] = 1.80 M,[PCl3] = 1.80 M,and [Cl2] = 1.80 M
D) [PCl5] = 3.96 M,[PCl3] = 3.83 M,and [Cl2] = 3.83 M

E) A) and B)
F) All of the above

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In a reaction mixture containing only reactants,what is the value of Q?


A) -1
B) 1
C) ∞
D) 0
E) It cannot be determined without concentrations.

F) B) and D)
G) B) and E)

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of CO2(g) . NH2COONH4(s) ⇌ 2 NH3(g) + CO2(g) Kc = 1.58 × 10-8 [NH3]eq = 2.3 × 10-3 M


A) 0.053 M
B) 3.6 × 10-11 M
C) 3.0 × 10-3 M
D) 6.9 × 10-6 M
E) 0.022 M

F) A) and E)
G) B) and D)

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